Transition metal-catalyzed allylic alkylations

  • U. Kazmaier, "Introduction of Allylic Side Chains onto Peptides by Pd(0)-Catalyzed Ester Enolate Claisen Rearrangement", J. Org. Chem. 1994, 59, 6667-6670.
  • U. Kazmaier, F. L. Zumpe, "Chelated Enolates of Amino Acid Esters—Efficient Nucleophiles in Palladium‐Catalyzed Allylic Substitutions", Angew. Chem. 1999, 111, 1572-1574; Angew. Chem. Int. Ed. Engl. 1999, 38, 1468-1470.
  • U. Kazmaier, F. L. Zumpe, "Palladium‐Catalyzed Allylic Alkylations without Isomerization—Dream or Reality?", Angew. Chem. 2000, 112, 805-807; Angew. Chem. Int. Ed. Engl. 2000, 39,802-804.
  • U. Kazmaier, S. Maier, F. L. Zumpe, "A Journey from Amino Acid and Peptide Chemistry to Palladium and Back", Synlett 2000, 1523-1535.
  • U. Kazmaier, F. L. Zumpe, "Chelated Enolates of Amino Acid Esters – new Efficient Nucleo­philes for Isomerization-free Stereoselective Palladium-Catalyzed Allylic Substitutions", Eur. J. Org. Chem. 2001, 4067-4076.
  • T. D. Weiß, G. Helmchen, U. Kazmaier, "Synthesis of amino acid derivatives via enantio- and diastereoselective Pd-catalyzed allylic substitutions with a non-stabilized enolate as nucleophile", J. Chem. Soc. Chem. Commun. 2002, 1270-1271.
  • M. Pohlman, U. Kazmaier, T. Lindner, "Allylic Alkylation versus Michael induced Ring Closure – Chelated Enolates as versatile Nucleophiles", J. Org. Chem. 2004, 69, 6909-6912.
  • U. Kazmaier, T. Lindner, " Efficient 1,5-Chirality Transfer in Palladium-Catalyzed Allylic Alkylations of Chelated Amino Acid Ester Enolates", Angew. Chem. 2005, 117, 3368-3371; Angew. Chem. Int. Ed. 2005, 44, 3303-3306.
  • T. Lindner, U. Kazmaier, "Substrate controlled palladium catalyzed allylic alkylations of chelated enolates – scope and limitations", Adv. Synth. Catal. 2005, 347, 1687-1695.
  • U. Kazmaier, D. Stolz, "Regio‐ and Stereoselective Rhodium‐Catalyzed Allylic Alkylations of Chelated Enolates", Angew. Chem. 2006, 118, 3143-3146; Angew. Chem. Int. Ed. 2006, 45, 3072-3075.
  • U. Kazmaier, J. Deska, A. Watzke, "Highly Stereoselective Allylic Alkylations of Peptides", Angew. Chem. 2006, 118, 4973-4976; Angew. Chem. Int. Ed. 2006, 45, 4855-4858.
  • K. Krämer, U. Kazmaier, "Isomerization-Free Allylic Alkylations of Terminal π-Allyl Palladium Complexes", J. Org. Chem. 2006,71, 8950-8953.
  • J. Deska, U. Kazmaier, "Stereoselective Syntheses and Reactions of Stannylated Peptides", Angew. Chem. 2007, 119, 4654-4657; Angew. Chem. Int. Ed. 2007, 46, 4570-4573.
  • J. Deska, U. Kazmaier, "Highly Stereoselective Peptide Modifications via Palladium Cataly­zed Allylic Alkylations of Chelated Peptide Enolates", Chem. Eur. J. 2007, 13, 6204-6211.
  • U. Kazmaier, D. Stolz, K. Krämer, F. Zumpe, "Influences on the Regioselectivity of Palladium-catalyzed Allylic Alkylations", Chem. Eur. J. 2008, 14, 1322-1329.
  • K. Krämer, J. Deska, C. Hebach, U. Kazmaier, "A straightforward approach towards glycoamino acids and glycopeptides via Pd-catalysed allylic alkylation", Org. Biomol. Chem. 2009, 7, 103-110.
  • A. Bayer, U. Kazmaier, "Highly Regioselective Ruthenium-catalyzed Allylic Alkylations of Chelated Enolates", Org. Lett. 2010, 12, 4960–4963.
  • S. Datta, U. Kazmaier, "Stereoselective palladium-catalyzed allylic alkylations of peptide amide enolates", Org. Biomol. Chem. 2011, 9, 872–880.
  • C. Bukovec, U. Kazmaier, "Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides", Org. Biomol. Chem. 2011, 9, 2743–2750.
  • S. Hähn, U. Kazmaier, "Chemoselective Rh-Catalyzed Allylic Alkylations of Chelated Enolates using Dienylcarbonates", Eur. J. Org. Chem. 2011, 4931–4939.
  • J. Gorges, A. Ullrich, U. Kazmaier, "A Straightforward Approach towards Ferrocenyl Amino Acids and Peptides via Allylic Alkylation", Eur. J. Org. Chem. 2013, 4372–4378.
  • S. Thies, U. Kazmaier, "Synthesis of α-Amino-γ-lactones via Pd-catalyzed intramolecular allylic alkylation of sarcosine allyl amides", Eur. J. Org. Chem. 2014, 1695–1707.
  • A. Bayer, U. Kazmaier, "[(p-cymene)RuCl2]2, an Efficient Catalyst for Highly Regioselective Allylic Alkylations of Chelated Amino Acid Ester Enolates", Chem. Eur. J. 2014, 20, 10484–10491.
  • A. Bayer, U. Kazmaier, "Ruthenium-catalyzed Allylic Alkylations of Chelated Enolates using Vinyl Dioxolanon-2-ones", J. Org. Chem. 2014, 79, 8498−8504.
  • K. Huwig, K. Schultz, U. Kazmaier, "Regio- and Stereoselective Modification of Chiral a-Amino Ketones by Pd-Catalyzed Allylic Alkylation", Angew. Chem. 2015, 127, 9248–9251; Angew. Chem. Int. Ed. 2015, 54, 9120–9123.
  • A. Kiefer, D. Gawas, U. Kazmaier, "A flexible Route towards α-Hydroxyesters via Pd-catalyzed allylic alkylations", Eur. J. Org. Chem. 2015, 5810–5816.
  • U. Kazmaier, "Non-stabilized enolates – versatile nucleophiles in transition metal-catalysed allylic alkylations", Org. Chem. Front. 2016, 3, 1541−1560.
  • M. Kohr, U. Kazmaier, "Halogenated allyl alcohol derivatives – versatile dielectrophiles for palladium-catalyzed allylic alkylations", Eur. J. Org. Chem. 2019, 2843–2849.
  • A. Horn, U. Kazmaier, "Stereoselective Modification of N-(α-Hydroxyacyl)-glycinesters via Palladium-Catalyzed Allylic Alkylation", Org. Lett. 2019, 21, 4595–4599.
  • C. Prudel, K. Huwig, U. Kazmaier, "Stereoselective Allylic Alkylations of Amino Ketones and their Application in the Synthesis of Highly Functionalized Piperidines", Chem. Eur. J. 2020, 26, 3181–3188.